Reactions of MoOCl4 with 1-Methylimidazole, 1,4-Diaminobutane, 2-Methylpyridine, 2-Methylpiperidine, Trimethylsilylimidazole and 1-Methylpyrrolidine
نویسندگان
چکیده
منابع مشابه
Reactions of Imidoyl Isoselenocyanates with Aromatic 2-Amino- N-heterocycles and 1-Methylimidazole
The reaction of N-phenylimidoyl isoselenocyanates 1 with 2-amino-1,3-thiazoles 10 in acetone proceeded smoothly at room temperature to give 4H-1,3-thiazolo[3,2-a] [1,3,5]triazine-4-selones 13 in fair yields (Scheme 2). Under the same conditions, 1 and 2-amino-3-methylpyridine (11) underwent an addition reaction, followed by a spontaneous oxidation, to yield the 3H-4l4-[1,2,4]selenadiazolo[1’,5’...
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Ab initio calculations at HF/6-31G* level of theory for geometry optimization and MP2/6-31G*//HF/6-31G* for a single point total energy calculation are reported for the importantenergy-minimum conformations and transition-state geometries of 1, 3-diazacyclohepta-1, 2-diene (2) and 1, 3-diazacycloocta-1, 2-diene (3). The C2 symmetric twist-chair (2-TC)conformation of 2 is calculated to be 7.4 kJ...
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ژورنال
عنوان ژورنال: Oriental Journal of Chemistry
سال: 2019
ISSN: 0970-020X,2231-5039
DOI: 10.13005/ojc/350324